Which of the following conditions favor the SN1 mechanism as opposed to the SN2 mechanism?

I. tertiary alkyl halide
II. primary alkyl halide
III. polar solvent

a. only I
b. only Il
c. I and Ill
d. Il and Ill

Answers

Answer 1

Answer:

c. I and Ill

Explanation:

SN1 mechanism is a unimolecular nucleophillic substitution reaction mechanism. "Unimolecular" implies that only one molecule is involved in the rate determining step and that is the alkyl halide. The rate determining step of SN1 reaction is the formation of a carbocation which subsequently reacts with a nucleophile in the fast step.

SN1 reactions occur mostly with tertiary alkyl halides due to sterric reasons. SN2 mechanism involves a crowded transition state because it is a concerted reaction mechanism. This is not possible in a tertiary alkyl halide due to the presence of bulky groups around the tertiary carbon atom hence tertiary alkyl halides do not undergo nucleophilic reaction by SN2 mechanism.

Secondly, polar solvents aid in the ionization of the alkyl halide thus assisting in the formation of the carbocation which participates in the second step of the reaction.


Related Questions

What is the characteristic of atoms

Answers

Answer:

Most of the atom is empty space. The rest consists of a positively charged nucleus of protons and neutrons surrounded by a cloud of negatively charged electrons. The nucleus is small and dense compared with the electrons, which are the lightest charged particles in nature.

Which segment of this graph shows a decreasing velocity?

Answers

Answer:

The segment of this graph that shows a decreasing velocity is the EF segment. AB and DE segments show that whatever was moving, in these segments was stopped. The segment BC shows an increase in velocity - the metres travelled were always more as the time went by.

Explanation:

EF segment
The segment of this graph that shows a decreasing velocity is the EF segment.

Which actions can be taken to plan for a drought check all that apply

Answers

Answer:

Can you attach a picture?

Explanation:

Hybridization of carbons in CH3-CH= C = CH2 is
a) sp3sp3, sp2 sp2
b) sp3. sp2, sp, sp3
c) sp3, sp3, sp2, sp3
d) sp3, sp2, sp, sp1

Answers

Answer:

A carbon atom bound to three atoms (two single bonds, one double bond) is sp2 hybridized and forms a flat trigonal or triangular arrangement with 120° angles between bonds. Notice that acetic acid contains one sp2 carbon atom and one sp3 carbon atom.

Suppose we have 100 g of each of the following substances. Which sample contain the greatest number of moles (F.W. = Formula Weight) A. HCI, F.W. = 36.5 B. H_2O, F.W. = 18.0 C. MgCO_3 F.W. = 84.3 D. AlCI_3, F.W. = 133.3 E. NaCl, F.W. = 58.4

Answers

Answer:

100 g of water has the highest number of moles

Explanation:

Recall that the number of moles is obtained as given mass/formula weight

For HCl;

number of moles = 100g/36.5g/mol = 2.7 moles

For H2O;

number of moles = 100g/18g/mol = 5.5 moles

For MgCO3

number of moles = 100g/84.3 g/mol = 1.2 moles

For AlCl3

number of moles = 100g/133.3g/mol = 0.75 moles

For NaCl

number of moles = 100g/58.4 g/mol = 1.7 moles

The enthalpy change of formation of carbon dioxide is –394 kJ mol–1. The enthalpy change of formation of water is –286 kJ mol–1. The enthalpy change of formation of methane is –74 kJ mol–1. What is the enthalpy change of combustion of methane?

Answers

The enthalpy change of combustion of methane : -892 kJ/mol

Further explanation  

The change in enthalpy in the formation of 1 mole of the elements is called enthalpy of formation  

The enthalpy of formation measured in standard conditions (25 ° C, 1 atm) is called the standard enthalpy of formation (ΔHf °)  

Determination of the enthalpy of formation of a reaction can be through a calorimetric experiment, based on the principle of Hess's Law, enthalpy of formation table, or from bond energy data  

The value of ° H ° can be calculated from the change in enthalpy of standard formation:  

∆H ° rxn = ∑n ∆Hf ° (product) - ∑n ∆Hf ° (reactants)  

Reaction for combustion of Methane (CH₄) :

CH₄ + 2O₂ → CO₂ + 2H₂O.

The elements in standard conditions are not included in the enthalpy calculations because the enthalpy of those elements under the standard conditions is zero(∆Hf °O₂ =0)

∆Hf ° CO₂ = -394 kj/mol

∆Hf ° H₂O=-286 kj/mol

∆Hf ° CH₄=-74 kJ/mol

The enthalpy change of combustion of methane :

[tex]\tt \Delta H_{rxn}=\Delta H_f~CO_2+2.\Delta H_fH_2O-(\Delta H_fCH_4)\\\\\Delta H_{rxn}=(-394-2.-286)-(-74)\\\\\Delta H_{rxn}=-892~kJ/mol[/tex]

Answer:

-655

Explanation:

ye

Molecules have Question 8 options: A) only kinetic energy. B) neither kinetic nor potential energy. C) only potential energy. D) both potential and kinetic energy.

Answers

The answer is C. only potential energy

What is the degree of oxidation of a simple substance​

Answers

Answer: The oxidation state of a free element (uncombined element) is zero. For a simple (monoatomic) ion, the oxidation state is equal to the net charge on the ion. For example, Cl– has an oxidation state of -1. When present in most compounds, hydrogen has an oxidation state of +1 and oxygen an oxidation state of −2.

Hope this helps...... Stay safe and have a Merry Christmas!!!!!!!!!!! :D

Explanation:

What is the final concentration of a hydrogen peroxide solution if 600 mL of a 1.2M solution was diluted to 1.0 L?

Answers

Problem #1: If you dilute 175 mL of a 1.6 M solution of LiCl to 1.0 L, determine the new concentration of the solution.

Solution:

M1V1 = M2V2

(1.6 mol/L) (175 mL) = (x) (1000 mL)

x = 0.28 M

Note that 1000 mL was used rather than 1.0 L. Remember to keep the volume units consistent.

Problem #2: You need to make 10.0 L of 1.2 M KNO3. What molarity would the potassium nitrate solution need to be if you were to use only 2.5 L of it?

Solution:

M1V1 = M2V2

(x) (2.5 L) = (1.2 mol/L) (10.0 L)

x = 4.8 M

Please note how I use the molarity unit, mol/L, in the calculation rather than the molarity symbol, M.

Problem #3: How many milliliters of 5.0 M copper(II) sulfate solution must be added to 160 mL of water to achieve a 0.30 M copper(II) sulfate solution?

Solution:

M1V1 = M2V2

(5.00 mol/L) (x) = (0.3 mol/L) (160 + x)

5x = 48 + 0.3x

4.7x = 48

x = 10. mL (to two sig figs)

The solution to this problem assumes that the volumes are additive. That's the '160 + x' that is V2.

Problem #4: What volume of 4.50 M HCl can be made by mixing 5.65 M HCl with 250.0 mL of 3.55 M HCl?

Solution:

Here is the first way to solve this problem:

M1V1 + M2V2 = M3V3

(3.55) (0.250) + (5.65) (x) = (4.50) (0.250 + x)

Where x is volume of 5.65 M HCl that is added

(0.250 + x) is total resultant volume

0.8875 + 5.65x = 1.125 + 4.50 x

1.15x = 0.2375

x= 0.2065 L

Total amount of 4.50 M HCl is then (0.250 + 0.2065) = 0.4565 L

Total amount = 456.5 mL

Here is the second way to solve this problem:

Since the amount of 5.65 M added is not asked for, there is no need to solve for it.

M1V1 + M2V2 = M3V3

(3.55) (250) + (5.65) (x − 250) = (4.50) (x)

That way, x is the answer you want, the final volume of the solution, rather than x being the amount of 5.65 M solution that is added.

Problem #5: A 40.0 mL volume of 1.80 M Fe(NO3)3 is mixed with 21.5 mL of 0.808M Fe(NO3)3 solution. Calculate the molar concentration of the final solution.

Which one is a decomposition reaction?​

Answers

Answer:

b no

Explanation:

because it is decomposing into two elements

The Answer is b :)))

Does the octet rule state that all elements except Hydrogen and Helium want eight (8) valence electrons?

Answers

Answer:

yes

Explanation:

Medicationswith names ending in ER,CR,XR,and SR indicate they are __ medications a: extended or controlled release b: oral c: chewable d: allergy

Answers

Answer: a: extended or controlled release

Explanation:

Which of the following equations is balanced?

Answers

Answer:

wheres the image

Explanation:

How many molecules of H2 will react with one molecule of the following triglyceride? CH2-O-C-(CH)14CH CH O-C-(CH)CH CH (CH)-CH CH2-O-C-(CH)16CH a. 1 b.3 c. 4 d. 6

Answers

Answer:

1

Explanation:

The full question is shown in the image attached.

If we look at the structure closely, we will discover that there is only one C=C double bond in the molecule.

It is worthy of note that hydrogen (H2) only reduces the C=C double bond. it does not affect any other bond in the molecule.

Hence, only one molecule of H2 is required to reduce one C=C bond present.

What is the freezing point in °C) of a 0.195 m
aqueous solution of K2S?
Enter your rounded answer with
3 decimal places.
K for water = 1.86 °C/m

Answers

Answer:

[tex]T_S=-1.09\°C[/tex]

Explanation:

Hello!

In this case, since the freezing point depression for a solution is computed via:

[tex](T_S-T_W)=-imK_f[/tex]

Whereas TW is the freezing temperature of water, TS that of the solution, i the van't Hoff's factor (3 for K2S as it ionizes properly), m the molality of the solution and Kf the freezing point constant of water. Thus, we plug in to obtain:

[tex](T_S-0\°C)=-3*0.195m*1.86\frac{\°C}{m}\\\\T_S=-1.09\°C[/tex]

Best regards!

The correct answer is -1.088. (Don't forget the negative sign).

The base that will NOT combine with 2-deoxyribose to form a nucleic acid is _____.

Answers

Answer:

Uracil

Explanation:

The base that will NOT combine with 2-deoxyribose to form a nucleic acid is Uracil.

2-deoxyribose is a pentose sugar found in the DNA (Deoxyribonucleic acid). It is devoid of oxygen in its 2' position. The bases found in DNA are Adenine, Guanine, Cytosine and Thymine. Adenine, Guanine, and Cytosine are also found in RNA (Ribonucleic acid). Thymine is not present in RNA, it is only found in DNA. The base found in RNA is Uracil which in turn is not present in DNA. The five carbon sugar present in RNA is ribose which combines with Uracil.

What type of radioactive decay will the isotopes 13B and 188Au most likely undergo?

a. Beta emission, positron emission
b. Beta emission, beta emission
c. Positron emission, beta emission
d. Positron emission, positron emission

Answers

Answer:

b. Beta emission, beta emission

Explanation:

A factor to consider when deciding whether a particular nuclide will undergo this or that type of radioactive decay is to consider its neutron:proton ratio (N/P).

Now let us look at the N/P ratio of each atom;

For B-13, there are 8 neutrons and five protons N/P ratio = 8/5 = 1.6

For Au-188 there are 109 neutrons and 79 protons N/P ratio = 109/79=1.4

For B-13, the N/P ratio lies beyond the belt of stability hence it undergoes beta emission to decrease its N/P ratio.

For Au-188, its N/P ratio also lies above the belt of stability which is 1:1 hence it also undergoes beta emission in order to attain a lower N/P ratio.

Radioactive decay refers to the loss of energy by an unstable atomic nucleus as radiation. The substance having unstable nuclei is radioactive.

The correct answer is:

Option B. Beta emission, beta emission

The radioactive decay of 13B and 188 Au can be explained as:

1. Neutron proton ratio refers to the particular nuclei that will undergo what type of radioactive decay.

For B-13, there are 8 neutrons and 5 protons, thus, the ratio is 1.6.For Au -188, there are 109 neutrons and 79 protons, thus, the ratio is 1.4.

2. In the B-13 element, the N/P ratio is beyond the stability of the atom, thus, it will emit beta emission to reduce the N/P ratio.

3. Similarly, the N/P ratio of the Au-188 is above the stability of the atom, thus, it undergoes the beta emission to reduce the N/P ratio.

Thus, the correct answer is Option B.

To know more about radioactive decay, refer to the following link:

https://brainly.com/question/14077220

In which scenarios would the amount of substance remaining be 200 mg? Select all that apply. 800 mg of a radioactive substance with a half-life of 2 years after decaying for 4 years 1,000 mg of a radioactive substance with a half-life of 5 years after decaying for 20 years 300 mg of a radioactive substance with a half-life of 1 year after decaying for 1 year 600 mg of a radioactive substance with a half-life of 6 hours after decaying for 18 hours 400 mg of a radioactive substance with a half-life of 8 hours after decaying for 8 hours

Answers

Answer:

e)  400 mg of a radioactive substance with a half-life of 8 hours after decaying for 8 hours

a) 800 mg of a radioactive substance with a half-life of 2 years after decaying for 4 years.

Explanation:

a) 800 mg of a radioactive substance with a half-life of 2 years after decaying for 4 years.

Number of half lives passed = Time elapsed/ half life

Number of half lives passed = 4 year/2 year

Number of half lives passed = 2

at time zero = 800 mg

At first half life = 800 mg/2 = 400 mg

At 2nd half life = 400 mg/2 = 200 mg

b) 1,000 mg of a radioactive substance with a half-life of 5 years after decaying for 20 years

Number of half lives passed = Time elapsed/ half life

Number of half lives passed = 20 year/ 5 year

Number of half lives passed = 4

at time zero = 1000 mg

At first half life = 1000 mg/2 = 500 mg

At 2nd half life = 500 mg/2 = 250 mg

At 3rd half life = 250 mg/2 =  125 mg

At 4th half life = 125 mg/2 = 62.5 mg

c) 300 mg of a radioactive substance with a half-life of 1 year after decaying for 1 year

Number of half lives passed = Time elapsed/ half life

Number of half lives passed = 1 year/ 1 year

Number of half lives passed = 1

at time zero = 300 mg

At first half life = 300 mg/2 = 150 mg

d) 600 mg of a radioactive substance with a half-life of 6 hours after decaying for 18 hours

Number of half lives passed = Time elapsed/ half life

Number of half lives passed = 18 hours / 6 hours

Number of half lives passed = 3

at time zero = 600 mg

At first half life = 600 mg/2 = 300mg

At 2nd half life = 300 mg/2 = 150 mg

At 3rd half life = 150 mg/2 =  75 mg

e)  400 mg of a radioactive substance with a half-life of 8 hours after decaying for 8 hours

Number of half lives passed = Time elapsed/ half life

Number of half lives passed = 8 hours / 8 hours

Number of half lives passed = 1

at time zero = 400 mg

At first half life = 400 mg/2 = 200 mg

A baseball struck by a bat flies away from the batter because
of:
a) Normal force
b) Friction
c) Electrical Force
O d) Applied Force

Answers

Answer:

the answer is applied force

Q5. Why are some salts acidic when others are neutral?

Answers

The pH will remain neutral at 7. Halides and alkaline metals dissociate and do not affect the H+ as the cation does not alter the H+ and the anion does not attract the H+ from water. This is why NaCl is a neutral salt.

How many neutrons are there in a neutral argon atom? Show how you found your answer on your scratch paper.

Answers

there are 22 neutrons in an argon atom. you simply subtract the proton count (atomic number) from the average atomic mass. WORK: 40-18=22

A fish company delivers 15 kg of salmon 4.7 kg Of crab and 1.76 kg of oysters to your seafood restaurant what is the total mass in kilograms of the seafood

Answers

Answer:

21.46 kg.

Explanation:

Hello!

In this case, when a variety of measurements are said to contribute to a total, we understand we need to add them all up in order to get that total; in such a way, since the given seafood is composed by 15 kg of salmon, 4.7 kg of crab and 1.76 kg of oysters, the total mass turns out:

[tex]m_T=15kg+4.7kg+1.76kg\\\\m_T=21.46kg[/tex]

Best regards!

What happens when sodium and sulfur combine?
A) each sodium atom gains one electron
B) each sulfur atom loses one electron
C) each sodium atom loses one electron
D) each sulfur atom gains one electron

Answers

Answer:

BBBBBBBB ITS B

Explanation:

How many grams are 1.2 x 10^-2 moles of K3PO4

Answers

Answer:

2.5471951319999997

Explanation:

Oxidation of a secondary alcohol results in the formation of a(n):________. a) tertiary alcohol b) acid c) aldehyde d) ketone

Answers

Answer:

A. Tertiary alcohol

Explanation:

Secondary alcohols are oxidized to ketones - and that's it. For example, if you heat the secondary alcohol propan-2-ol with sodium or potassium dichromate(VI) solution acidified with dilute Sulphuric acid, you get propanone formed. Playing around with the reaction conditions makes no difference whatsoever to the product.

What mass of nitrogen occupies a volume of 11.2 L, if 4.20 g of nitrogen occupies 100. L?

Answers

Answer:

0.47 g

Explanation:

From the question given above, we obtained the following information:

4.20 g of nitrogen occupies 100 L.

We can obtain the mass of nitrogen that occupied 11.2 L by doing the following:

4.20 g of nitrogen occupies 100 L.

Therefore, Xg of nitrogen will occupy 11.2 L i.e

Xg of nitrogen = (11.2 × 4.2) / 100

Xg of nitrogen = 0.47 g

From the calculation made above, 0.47 g of nitrogen will occupy 11.2 L

What happened to the celery if you put in food color water ​

Answers

Answer:

the celery would change colour!

Explanation:

Q. The entropy of the system will usually increase when

answer choices

A)a molecule is broken into two or more smaller
molecules

B)a reaction occurs that results in an increase in
the number of moles of gas

C)a solid changes to a liquid

D)all of these

Answers

Answer:

D

Explanation:

Molecules Have?

A. Only kinetic energy
B. Only potential energy
C. Both kinetic and potential energy
D. Neither potential nor kinetic

Answers

Answer:

C

Explanation:

Because molecules of solids don't move

while molecules of liquids and gases move.

I Hope this helps!!.

In which type of mirror do you see the most realistic virtual image
Plane
Convex
Concave
Duplex

Answers

Phan

convex

concave

duplex

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